You can buy them from Enthier in the Hall of Countenance in the College of Winterhold.

ya at the college, he can only sell you, i think 2 hearts every 48 hours. So just rest a lot after you buy his stock, if you want more

Im not 100% sure, but ive seen daedra hearts for sale, and ive never been in the college. I would try the caravan, im pretty certain they carry it sometimes.

go to dawnstar and theresd a museum that you can do a quest which you get 4 for doing at the end for killing 4 monsters which spawn once a week
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Hes not selling to me? kay:

You must do the all of the Thieves Guild quests up too "Hard Answers" (including Hard Answers) for Enthir to provide his services.

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Also he only sells his goods at the Hall of Attainment.

Oh thanks . :y:

There is a quest to collect the 3 pieces of mehrunes razor. The quest starts when you get a pamphlet to visit the museum in winterhold. You have the oppurtunity to get 4 daedra hearts. You must kill all of them but just Fus Ro Dah the two off the mountain and go inside the door to find 2 more dremoras.